Anne Victorio (Angelica Panganiban), a brand manager, is determined for the past ten years to always choose what is right and become the mother and wife her mother never was. Her marriage to the equally successful Geoff (Dingdong Dantes) is the envy among her peers. Unknown to most people, Anne has been betrayed by Geoff several times and she is just putting up a façade of an untroubled family life.

After finally deciding to file for annulment and live separately from her husband, Anne meets Brian (Paulo Avelino), an enigmatic and carefree man who is also recently separated from his wife. Brian makes Anne happy again, and despite Anne’s earlier apprehensions, she decides to enter into a relationship with Brian even is she still technically married to Geoff.

But as Anne rediscovers a new life as an “unmarried woman,” complications arise as she realizes balances the demands of her passionate new relationship with her obligations as a mother and her still unresolved and complicated feelings for her soon-to-be ex-husband.